16 research outputs found
Real-time event classification in field sport videos
The paper presents a novel approach to real-time event detection in sports broadcasts. We present how the same underlying audio-visual feature extraction algorithm based on new global image descriptors is robust across a range of different sports alleviating the need to tailor it to a particular sport. In addition, we propose and evaluate three different classifiers in order to detect events using these features: a feed-forward neural network, an Elman neural network and a decision tree. Each are investigated and evaluated in terms of their usefulness for real-time event classification. We also propose a ground truth dataset together with an annotation technique for performance evaluation of each classifier useful to others interested in this problem
Sulfolane: Magic Extractor or Bad Actor? Pilot-Scale Study on Solvent Corrosion Potential
The sulfur-containing derivatives and their metabolites, regarded as ‘old devils of green’ chemistry, constitute a relevant class of air/water/soil contaminants in over-polluted world. In fact, some industrially-engineered solvents have become environmentally unfavorable. An attractive alternative to commonly used industrial liquids is sulfolane (C4H8SO2), an anthropogenic medium. The main objective of this paper is the comprehensive review focusing mainly on the state-of-the-art aspects of the sulfolane synthesis, application of sulfolane as an extractive solvent due to its ‘unique’ physicochemical properties as well as the potential of sulfolane to cause equipment corrosion and subsequent spills. The potential risk for groundwater contamination, danger for human health and ways of sulfolane biodegradation were briefly reviewed as well. Interestingly, the analysis performed on data stored in the Reaxys database revealed an alternating tendency of waxing and waning interest in sulfolane during the space of the last fifty years. Moreover, the primary goal of the presented case study was to verify applicability of industrial, multi-electrochemical technique for reliable detection of corrosion in low conductive process fluids. Several aspects of corrosion measurement including the impact of process parameters (temperature) and impurities (oxygen and chlorides) on stainless steel corrosion in pure sulfolane were investigated briefly
Nine-Axis IMU sensor fusion using the AHRS algorithm and neural networks
This paper presents data processing method for Attitude
Heading and Reference System (AHRS) based on Artificial
Neural Networks (ANN). The system consist of MEMS (Micro
Electro-Mechanical Systems) based on Inertial Measurement
Unit (IMU) consisting of tri-axis gyroscopes, accelerometers and
magnetometers providing three dimensional linear accelerations
and angular rates. Training data was generated by simulation
fusion of samples collected during the flight of Quadcopter.
The presented results shows proper functioning of the neural
network. Moreover, the presented system provide the possibility
to easily add other sensors e.g. GPS, in order to achieve better
performance
Electrochemical corrosion monitoring in low conductive fluid : pilot-scale study on sulfolane corrosion potential
Solvents are a group of chemical compounds that are widely used in organic synthesis.
Taking into account the chemical nature, solvents are divided into protic and aprotic ones. An
attractive alternative to commonly used industrial extractive liquids is an anthropogenic,
organosulfur medium—sulfolane. Sulfolane is a five-membered heterocyclic sulfur–organic
compound from the group of sulfones (R-SO2-R’, where R/R’ is alkyl, alkenyl, or aryl), which
contains an apolar hydrocarbon backbone and a polar functional group. It is a selective solvent in
the liquid–liquid and liquid–vapor extraction processes used for the removal of close-boiling
alkanes from cycloalkanes or for the separation of compounds with different degrees of saturation
and polarity in the extractive rectification of arenes from non-aromatic saturated hydrocarbon
mixtures. In standard conditions sulfolane is not an aggressive solvent for steel, but at higher
temperature (170–180 °C) and oxygen availability, it may be decomposed and subsequently some
corrosive (by-)products can be formed. The primary purpose of the presented pilot-case
examination was to verify applicability of the industrial, multi-electrochemical technique for
reliable detection of the corrosion processes in low conductive fluids
Electrochemical corrosion monitoring in low conductive fluid : pilot-scale study on sulfolane corrosion potential
Solvents are a group of chemical compounds that are widespread in the organic chemistry. Taking into account the chemical nature, solvents are divided into the protic and aprotic ones. An attractive alternative to commonly used indus-trial extractive liquids is an anthropogenic, organosulfur medium – sulfolane. Sulfolane is a five-membered heterocyclic sulfur-organic compound from the group of sulfones (ArSO2), which contains an apolar hydrocarbon backbone and a polar functional group. It is a selective solvent in the liquid-liquid and liquid-vapour extraction processes used for the removal of close-boiling alkanes from cycloalkanes or for the separation of compounds with different degree of satu-ration and polarity in the extractive rectification of arenes from non-aromatic saturated hydrocarbon mixtures. In the standard conditions sulfolane is not an aggressive solvent for steel, but at higher temperature (170-180ºC) and oxygen availability, it may be decomposed and subsequently some corrosive (by-)prod-ucts can be formed. The primary purpose of the presented pilot-case study was to verify the applicability of the industrial, multi-electrochemical technique for reliable detection of the corrosion processes in the low conductive fluids
Real-time corrosion monitoring of AISI 1010 carbon steel with metal surface mapping in sulfolane
Solvents are widely used in organic synthesis. Sulfolane is a five-membered heterocyclic
organosulfur sulfone (R-SO2-R’, where R/R’ is alkyl, alkenyl, or aryl) and an anthropogenic medium
commonly used as industrial extractive solvent in the liquid-liquid and liquid-vapor extraction
processes. Under standard conditions sulfolane is not aggressive towards steel, but at higher
temperatures and in oxygen, water, or chlorides presence, it can be decomposed into some corrosive
(by-)products with generation of SO2 and subsequent formation of corrosive H2SO3. This pilot-case
study provides data from laboratory measurements performed in low conductivity sulfolane-based
fluids using an industrial multi-electrochemical technique for reliable detection of corrosion processes.
In particular, a comprehensive evaluation of the aqueous phase impact on general and localized
corrosion of AISI 1010 carbon steel in sulfolane is presented. Assessment of corrosive damage was
carried out using an open circuit potential method, potentiodynamic polarization curves, SEM/EDS
and scanning Kelvin probe technique. It was found that an increase in the water content (1–3 vol.%)
in sulfolane causes a decrease in the corrosion resistance of AISI 1010 carbon steel on both uniform
and pitting corrosion due to higher conductance of the sulfolane-based fluids
Biological activities and ADMET-related properties of novel set of cinnamanilides
A series of nineteen novel ring-substituted N-arylcinnamanilides was synthesized and
characterized. All investigated compounds were tested against Staphylococcus aureus as the reference
strain, two clinical isolates of methicillin-resistant S. aureus (MRSA), and Mycobacterium tuberculosis.
(2E)-N-[3-Fluoro-4-(trifluoromethyl)phenyl]-3-phenylprop-2-enamide showed even better activity
(minimum inhibitory concentration (MIC) 25.9 and 12.9 M) againstMRSAisolates than the commonly
used ampicillin (MIC 45.8 M). The screening of the cell viability was performed using THP1-Blue
NF- B cells and, except for (2E)-N-(4-bromo-3-chlorophenyl)-3-phenylprop-2-enamide (IC50 6.5 M),
none of the discussed compounds showed any significant cytotoxic e ect up to 20 M. Moreover,
all compounds were tested for their anti-inflammatory potential; several compounds attenuated the
lipopolysaccharide-induced NF- B activation and were more potent than the parental cinnamic acid.
The lipophilicity values were specified experimentally as well. In addition, in silico approximation
of the lipophilicity values was performed employing a set of free/commercial clogP estimators,
corrected afterwards by the corresponding pKa calculated at physiological pH and subsequently
cross-compared with the experimental parameters. The similarity-driven property space evaluation
of structural analogs was carried out using the principal component analysis, Tanimoto metrics,
and Kohonen mapping
The 42nd Symposium Chromatographic Methods of Investigating Organic Compounds : Book of abstracts
The 42nd Symposium Chromatographic Methods of Investigating Organic Compounds : Book of abstracts. June 4-7, 2019, Szczyrk, Polan